Interfacial Engineering Approach to Pattern Resilient Polymer Photonic Crystals with Temperature‐Responsive Optical Properties

نویسندگان

چکیده

Planar, 1D photonic crystals (1D-PCs) are stacks of alternating layers with different refractive indices, which can reflect specific wavelengths light through the formation a bandgap. Typical systems for 1D-PC fabrication possess relatively limited thermal and/or chemical stabilities and may require several steps producing patterned features. Additionally, enabling stimuli-responsive behaviors in 1D-PCs often achieved complex chemistries that might be difficult to scale-up due associated cost energy consumption, presenting challenges toward their implementation practical systems. Herein, sequential depositions phenolic resin (resol) poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), two low-cost reagents broadly used industry, bright prepared high stability at long exposure times. Furthermore, spatial differences reflectance behavior thus resulted patterns demonstrated simple, generalizable interfacial engineering approach controls surface wettability PVDF-HFP layer. Stimuli-responsive is imparted into system by leveraging semicrystalline nature provide on-demand switchable light-reflecting upon elevated temperatures. Overall, this work demonstrates simple efficient technique develop excellent stability, ease patterning, thermoresponsive from precursors, potentially broader use wide array nanotechnological applications.

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ژورنال

عنوان ژورنال: Advanced Materials Interfaces

سال: 2022

ISSN: ['2196-7350']

DOI: https://doi.org/10.1002/admi.202102083